Development of more labile low electron count Co(I) sources: mild, catalytic functionalization of activated alkanes using a [(Cp*Co)2-μ-(η4:η4-arene)] complex.
نویسندگان
چکیده
Catalytic transfer dehydrogenation of silyl protected amines, requiring sp(3) C-H bond activation, is mediated by a bridging arene complex of the type [(Cp*Co)(2)-μ-(η(4):η(4)-arene)] under mild conditions. Mechanistic and qualitative rate studies establish the compound as a more reactive Co(I) source when compared to other known Cp*Co(I) complexes.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 48 3 شماره
صفحات -
تاریخ انتشار 2012